(2-Methyl-4-oxo-4H-pyran-3-olato-κ2 O 3,O 4)bis(triphenylphosphane-κP)copper(I)–triphenylphosphane–methanol (1/1/1)
نویسندگان
چکیده
In the title compound, [Cu(C(6)H(5)O(3))(C(18)H(15)P)(2)]·C(18)H(15)P·CH(3)OH, the pyran-4-one ring is appromimately planar (r.m.s deviation = 0.0138 Å), with the Cu(I) atom 0.451 (5) Å out of the plane. The Cu(I) atom has a distorted tetra-hedral coordination. The O-Cu-O angle is 80.07 (8)° and the P-Cu-P angle is 123.49 (3)°. The crystal packing is stablized by intra-molecular C-H⋯O inter-actions and inter-molecular C-H⋯O and O-H⋯O inter-actions.
منابع مشابه
Bis{μ-(E)-methyl 4-[(2-carbamothioylhydrazinylidene)methyl]benzoate-κ2 S:S}bis[iodido(triphenylphosphane-κP)copper(I)]
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